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Natural Deep Eutectic Solvent-Catalyzed Selenocyanation of Activated Alkynes via an Intermolecular H-Bonding Activation Process

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成果类型:
期刊论文
作者:
Wu, Chao;Xiao, Hai-Jing;Wang, Shu-Wen;Tang, Man-Sheng;Tang, Zi-Long;...
通讯作者:
He, Wei-Min
作者机构:
[Tang, Man-Sheng; Wu, Chao; Xiao, Hai-Jing; He, Wei-Min; Wang, Shu-Wen] Hunan Univ Sci & Engn, Dept Chem, Yongzhou 425100, Peoples R China.
[Wu, Chao; Tang, Zi-Long; Xia, Wen] Hunan Univ Sci & Technol, Minist Educ, Key Lab Theoret Organ Chem & Funct Mol, Xiangtan 411201, Peoples R China.
[Li, Wen-Feng; Cao, Zhong] Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410114, Hunan, Peoples R China.
通讯机构:
[He, Wei-Min] H
Hunan Univ Sci & Engn, Dept Chem, Yongzhou 425100, Peoples R China.
语种:
英文
关键词:
Deep eutectic solvent;Multicomponent reaction;Selenocyanation;Alkynes;H-bonding
期刊:
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
ISSN:
2168-0485
年:
2019
卷:
7
期:
2
页码:
2169-2175
基金类别:
We are grateful for financial support from the postfunded projects of Hunan University of Science and Engineering and the National Natural Science Foundation of China (no. 21877034).
机构署名:
本校为其他机构
院系归属:
化学与生物工程学院
摘要:
By employing cheap and biodegradable natural deep eutectic solvent as the catalyst and reaction media, the selective selenocyanation of activated alkynes via an intermolecular H-bonding activation pathway has been achieved, which allows for the efficient construction of various Z-vinyl selenol...

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