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Construction of hierarchically porous Mg-MOF-74 by defect engineering for high-efficiency CO₂ adsorption under ambient conditions

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成果类型:
期刊论文
作者:
Zhuo, Chao-Yue;Xiao, Pian-Pian;Li, Ziyi;Zhang, Yue-Fei
通讯作者:
Zhang, YF
作者机构:
[Zhuo, Chao-Yue; Zhang, Yue-Fei; Xiao, Pian-Pian; Li, Ziyi] Changsha Univ Sci & Technol, Sch Chem & Pharmaceut Engn, Hunan Prov Key Lab Mat Protect Elect Power &, Changsha 410114, Peoples R China.
通讯机构:
[Zhang, YF ] C
Changsha Univ Sci & Technol, Sch Chem & Pharmaceut Engn, Hunan Prov Key Lab Mat Protect Elect Power &, Changsha 410114, Peoples R China.
语种:
英文
关键词:
Mg-MOF-74;Propionic acid regulation;Hierarchical pore construction;CO 2 adsorption
期刊:
Chemical Engineering Journal
ISSN:
1385-8947
年:
2025
卷:
520
页码:
165655
基金类别:
Laboratory of Materials Protection for Electric Power and Transportation [2023CL03]; Changsha University of Science and Technology, P. R. China
机构署名:
本校为第一且通讯机构
院系归属:
化学与生物工程学院
摘要:
Mg-MOF-74 material with a hierarchical pore structure was successfully prepared by regulating the defects through propionic acid. The derived materials were analyzed with X-ray diffraction, scanning electron microscopy, FT-IR, X-ray photoelectron spectroscopy, thermogravimetry analysis, elemental analysis, and nitrogen adsorption. Results show that a low concentration of propionic acid (n DHTA :n PA = 2:1) introduces a mesoporous structure while maintaining the material's crystallinity. This modification significantly increased the specific su...

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