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O-Doping Boosts the Electrochemical Oxygen Reduction Activity of a Single Fe Site in Hydrophilic Carbon with Deep Mesopores.

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成果类型:
期刊论文
作者:
Ni, Wenpeng;Gao, Yang;Zhang, Yi;Younus, Hussein A.;Guo, Xiaoguang;...
通讯作者:
Zhang, Yan;Zhang, Shiguo
作者机构:
[Ma, Chao; Gao, Yang; Zhang, Yi; Zhang, Y; Zhang, Shiguo; Zhang, Yan; Ni, Wenpeng; Younus, Hussein A.] Hunan Univ, Coll Mat Sci & Engn, State Key Lab Adv Design & Mfg Vehicle Body, Changsha 410004, Hunan, Peoples R China.
[Guo, Xiaoguang] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China.
[Duan, Junfei] Changsha Univ Sci & Technol, Sch Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China.
[Zhang, Jiaheng] Harbin Inst Technol Shenzhen, Sch Mat Sci & Engn, Shenzhen 518055, Guangdong, Peoples R China.
通讯机构:
[Zhang, Y; Zhang, SG] H
Hunan Univ, Coll Mat Sci & Engn, State Key Lab Adv Design & Mfg Vehicle Body, Changsha 410004, Hunan, Peoples R China.
语种:
英文
关键词:
O-doping;carbon materials;carbonyl group;oxygen reduction reaction;single-atom catalysts
期刊:
ACS Applied Materials & Interfaces
ISSN:
1944-8244
年:
2019
卷:
11
期:
49
页码:
45825-45831
基金类别:
This work was financially supported by the National Natural Science Foundation of China (Grant Nos. 21872046, 51772089,and 51902100), the Outstanding Youth Scientist Foundation of Hunan Province (Grant No. 2018JJ1009), the Youth 1000 Talent Program of China, the Science and Technology Innovation Platform and Talent Plan of HunanPvovince (Grant No. 2017XK2023),the Research and Development Plan of Key Areas in Hunan Province (Grant No. 2019GK2235), the China Postdoctoral Science Foundation (2018M642971), and the Youth Scientist Foundation of Hunan Province (Grant No. 2019JJ50087),the National Key R&D Program of China (2017YFA0403402).
机构署名:
本校为其他机构
院系归属:
材料科学与工程学院
摘要:
Carbon-based electrocatalysts with single metal sites hold great potential for mechanism exploration via mimicking molecular catalysts, due to their distinct catalytic sites. In addition to metal atoms, the neighboring nonmetal heteroatoms such as N, S, and O atoms, which are widely detected in carbon-based single-atom catalysts, may also contribute to enhancing the electrochemical activity of single-metal centers. In this work, the boosting effect of O-doping toward the electrochemical oxygen reduction reaction (ORR) was evaluated by both expe...

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