Many organic molecules have unique magnetic properties and can potentially serve as excellent molecular spin devices, which is worth exploring deeply. Here, the spin transport properties of Mn, Fe, Co and Cu porphyrin dimer devices are investigated based on the first principles method. The spin filtering efficiencies of these molecular devices are maintained at 100% within certain applied voltage ranges and magnetoresistance ratios are higher than 10(8)% which increase as the voltage increases. To explain the excellent spin-filtering and giant magnetoresistance effects, analysis of spin electr...
