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Nucleation effect of adipic acid metal salts in isotactic polypropylene

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成果类型:
期刊论文
作者:
Ren, Xiao-Qiong;Zhang, Yue-Fei*;He, Juan;Li, Yan
通讯作者:
Zhang, Yue-Fei
作者机构:
[Zhang, Yue-Fei; Li, Yan; Ren, Xiao-Qiong; He, Juan] Changsha Univ Sci & Technol, Sch Chem & Biol Engn, 960 South Wanjiali Rd, Changsha 410114, Hunan, Peoples R China.
通讯机构:
[Zhang, Yue-Fei] C
Changsha Univ Sci & Technol, Sch Chem & Biol Engn, 960 South Wanjiali Rd, Changsha 410114, Hunan, Peoples R China.
语种:
英文
关键词:
Chlorine compounds;Crystallization;Decomposition;Differential scanning calorimetry;Metals;Nucleation;Salts;Crystallization behavior;Crystallization peak temperatures;Double decomposition;Isotactic poly(propylene) (iPP);Isotactic polypropylene;Metal salt;Nucleation effect;Nucleation efficiency;Polypropylenes
期刊:
Journal of Thermal Analysis and Calorimetry
ISSN:
1388-6150
年:
2019
卷:
135
期:
6
页码:
3321-3328
基金类别:
Acknowledgements This work was financially supported by National Natural Science Foundation of China (Grant No. 21376031) and Scientific Research Fund of Hunan Provincial Education Department (Grant No. 16A004).
机构署名:
本校为第一且通讯机构
院系归属:
化学与生物工程学院
摘要:
A series of adipic acid metal salts as nucleating agents for isotactic polypropylene (iPP) were synthesized from adipic acid (Adi) and corresponding metal hydroxides or chlorides by neutralization or double decomposition reaction. The effect of different adipate on the crystallization and melting behavior of iPP were investigated by differential scanning calorimetry (DSC). The results indicated that after adding different metal salts of adipic acids, the crystallization peak temperature of nucleated iPP was increased by different degree. Adi, b...

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