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Design and Preparation of NiCoMn Ternary Layered Double Hydroxides with a Hollow Dodecahedral Structure for High-Performance Asymmetric Supercapacitors

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成果类型:
期刊论文
作者:
Chen, Yulian;Yang, Juan;Yu, Hao;Zeng, Junqing;Li, Guang;...
通讯作者:
Zheng, Liping(zlp33520@163.com);Wang, Xianyou(xywang@xtu.edu.cn)
作者机构:
[Li, Guang; Wang, Xianyou; Zheng, Liping; Yang, Juan; Yu, Hao; Zeng, Junqing; Chen, Yulian] Xiangtan Univ, Natl Base Int Sci & Technol Cooperat, Natl Local Joint Engn Lab Key Mat New Energy Stor, Sch Chem,Hunan Prov Key Lab Electrochem Energy St, Xiangtan 411105, Hunan, Peoples R China.
[Chang, Baobao] Zhengzhou Univ, Minist Educ, Key Lab Mat Proc & Mold, Zhengzhou 450001, Henan, Peoples R China.
[Wu, Chun] Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha 410114, Hunan, Peoples R China.
[Guo, Xiaowei; Chen, Gairong] Xinxiang Coll, Sch Chem & Mat Engn, Xinxiang 453003, Henan, Peoples R China.
通讯机构:
[Liping Zheng; Xianyou Wang] N
National Base for International Science & Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan University, Xiangtan, Hunan 411105, China
语种:
英文
关键词:
zeolitic imidazolate framework-67 (ZIF-67);ternary layered double hydroxides;hollow structure;nanosheets;asymmetric supercapacitors
期刊:
ACS Applied Energy Materials
ISSN:
2574-0962
年:
2022
卷:
5
期:
6
页码:
6772-6782
基金类别:
This work was financially supported by the Natural Science Foundation of Hunan Province, China (No. 13JJ4051), Specialized Research Fund for the Doctoral Program of Higher Education (No. 20134301130001), National Natural Science Foundation of China (Nos. 51302239, 51272221, and 51072173). The authors thank Shiyanjia Lab ( www.shiyanjia.com ) for the XPS test. The electrochemical testing in this work was aided by Jiangsu Donghua Test Technology Co., Ltd. ( www.dhtest.com ).
机构署名:
本校为其他机构
院系归属:
材料科学与工程学院
摘要:
Layered double hydroxides (LDHs) are prospective cathode materials for supercapacitors because of their outstanding theoretical specific capacitance and unique layered structure. However, the finite electroactive sites and cation species confine their practical application in supercapacitors. In this work, a hollow polyhedral ternary metallic Ni2CoMn1-LDH is prepared using zeolitic imidazolate framework-67 (ZIF-67) as the template. It has been found that the hollow dodecahedral structure constructed by thin nanosheets endows the Ni2CoMn1-LDH sa...

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