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Partnered Excited-State Intermolecular Proton Transfer Fluorescence (P-ESIPT) Signaling for Nitrate Sensing and High-Resolution Cell-Imaging

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成果类型:
期刊论文
作者:
Ma, Pan;Gong, Fuchun;Zhu, Hanming;Qian, You;He, Lingzhi;...
通讯作者:
Fuchun Gong
作者机构:
[Gong, Fuchun; Zhu, Hanming; Ma, Pan; Qian, You; He, Lingzhi; Xia, Jiaoyun; Cao, Zhong] Changsha Univ Sci & Technol, Coll Chem & Chem Engn, Changsha 410114, Peoples R China.
通讯机构:
[Fuchun Gong] C
College of Chemistry and Chemical Engineering, Changsha University of Science and Technology, Changsha 410114, China<&wdkj&>Author to whom correspondence should be addressed.
语种:
英文
关键词:
6-pyrenyl-2-pyridinone;ESIPT fluorophore;partnered-proton transfer;nitrite sensing;cell-imaging
期刊:
Molecules
ISSN:
1420-3049
年:
2022
卷:
27
期:
16
页码:
5164-
基金类别:
This work was financially supported by the Research Foundation of Education Bureau of Hunan Province (No.18A141) and the State Key Laboratory of Bio-organic and Natural Product Chemistry (No. SKLBNPC19250).
机构署名:
本校为第一机构
院系归属:
化学与生物工程学院
摘要:
Nitrite (NO2-) is a common pollutant and is widely present in the environment and in human bodies. The development of a rapid and accurate method for NO2- detection is always a very important task. Herein, we synthesized a partnered excited-state intermolecular proton transfer (ESIPT) fluorophore using the "multi-component one pot" method, and used this as a probe (ESIPT-F) for sensing NO2- ESIPT-F exhibited bimodal emission in different solvents because of the solvent-mediated ESIPT reaction. The addition of NO2- caused an obvious change in colors and tautomeric fluorescence due to the graft ...

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