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Crystal growth behavior and fluorescence properties of LaMgAl11O19:Eu3+ nano-powders prepared via sol-gel process

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成果类型:
期刊论文
作者:
Hu, Taotao;Huang, Wenzhi;Zhong, Ruiqi;Zhang, Jindong;Zeng, Na;...
通讯作者:
Huang, Wenzhi(huangwenzhi_kd@163.com)
作者机构:
[Wang, Yangyang; Huang, Wenzhi; Zhang, Jindong; Hu, Taotao; Zhong, Ruiqi] Natl Univ Def Technol, Coll Aerosp Sci & Engn, Sci & Technol Adv Ceram Fibers & Composites Lab, Changsha 410073, Peoples R China.
[Liu, Wanyu; Zeng, Na] Changsha Univ Sci & Technol, Sch Chem & Chem Engn, Hunan Prov Key Lab Mat Protect Elect Power & Trans, Changsha 410114, Peoples R China.
通讯机构:
[Wenzhi Huang] S
Science and Technology on Advanced Ceramic Fibers & Composites Laboratory, College of Aerospace Science and Engineering, National University of Defense Technology, Changsha, 410073, PR China
语种:
英文
关键词:
Sol-gel process;Nano-powders;Activation energy;Crystal growth behavior;Fluorescence
期刊:
Ceramics International
ISSN:
0272-8842
年:
2023
卷:
49
期:
7
页码:
10554-10565
基金类别:
Navi (Hunan, China); Natural Science Foundation of Hunan Province [2019JJ40337]
机构署名:
本校为其他机构
院系归属:
化学与生物工程学院
摘要:
LaMgAl11O19:Eu3+ (LMA:Eu3+) nano-powders were prepared via sol-gel process by controlling the amount of ethanol and AcOH in the raw solution. With the addition of ethanol, the activation energy for crystal growth of LMA:Eu3+ nano-powders was decreased from 69.10 ± 3.74 kJ/mol to 57.95 ± 2.62 kJ/mol, while the lowest activation energy of 57.95 ± 2.62 kJ/mol was obtained with the water/ethanol volume ratio of 1:3 and the AcOH/metal ions molar ratio of 1:1. However, there is less influence on the phase composition and microstructure of the powd...

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