期刊论文

Yuan, D;Zhang, YZ;Zhang, HT

英文

Journal of Materials Chemistry A

2050-7488

2023

11

27

14720-14727

10.1039/d3ta02117c

100 Talented Team of Hunan Province [XiangZu [2016] 91]; Natural Science Foundation of Hunan Province [2022JJ30613]; National Natural Science Foundation of China [21878308, 62174085]; Startup Foundation for Introducing Talent of NUIST [2021r091]

本校为第一且通讯机构

Electrolyte design provides a fundamental solution to address the irreversibility and instability of metallic Zn anodes for the fast-developing zinc-ion batteries, considering the increasing issue of their sustainability. Herein, a cellulose-complexing approach was developed for a ZnCl2-based eutectic electrolyte to reconstruct Zn2+ coordination, tune water activity and regulate the solid-electrolyte interface (SEI). In the case of deficient water, the oxygen atoms from the glucose unit were revealed to coordinate directly with Zn2+, resulting in the participation of cellulose in the solvation...