Purpose – The purpose of this paper was to investigate the effects of SO42- concentration on the corrosion behaviour of T23 and T12 steels in simulated water chemistry condition solution of 600 MW fossil-fired power boilers. Design/methodology/approach – The influence and mechanism of SO42- ions on the pitting corrosion of T23 and T12 steels in simulated oxygenated treatment water chemistry solution was studied using electrochemical potentiodynamic polarization scans and electrochemical impedance spectroscopy. Findings – The results showed t...