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Supramolecular Interaction-Driven Amorphization of Poly(aryl piperidine) Membranes for Enhanced Proton Conductivity

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成果类型:
期刊论文
作者:
Qianqian Cheng;Zutao Sheng;Mingjie Li;Wenjing Ye;Sangshan Peng;...
通讯作者:
Sangshan Peng<&wdkj&>Guang Zeng<&wdkj&>Qing He
作者机构:
[Qianqian Cheng; Mingjie Li; Wenjing Ye; Sangshan Peng; Qing He] State Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineer Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082 P. R. China
[Guang Zeng] School of Materials Science and Engineering, Changsha University of Science and Technology, Changsha, 410004 P. R. China
[Zutao Sheng] State Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineer Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082 P. R. China<&wdkj&>School of Materials Science and Engineering, Changsha University of Science and Technology, Changsha, 410004 P. R. China
通讯机构:
[Sangshan Peng; Guang Zeng; Qing He] S
School of Materials Science and Engineering, Changsha University of Science and Technology, Changsha, 410004 P. R. China<&wdkj&>State Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineer Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082 P. R. China
语种:
英文
关键词:
ion-conducting membranes;poly(aryl piperidine);redox flow batteries;supramolecular interactions
期刊:
Advanced Energy Materials
ISSN:
1614-6832
年:
2025
页码:
2405436
机构署名:
本校为通讯机构
院系归属:
材料科学与工程学院
摘要:
Non-fluorinated polymer membranes offer a commercially feasible solution for redox flow batteries (RFBs), yet their practical applications have been hampered by inherent challenges such as chemical instability and low ionic conductivity. In this study, the development of a series of ether-bond-free poly(aryl piperidine) membranes that address these limitations by introducing enhanced disorder in polymer chain packing through supramolecular interactions with organic acids, is presented. These interactions effectively disrupt densely packed polym...

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