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A MoS2 coating strategy to improve the comprehensive electrochemical performance of LiVPO4F

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成果类型:
期刊论文
作者:
Liu, Zhaomeng;Peng, Wenjie;Shih, Kaimin;Wang, Jiexi*;Wang, Zhixing;...
通讯作者:
Wang, Jiexi
作者机构:
[Peng, Wenjie; Guo, Huajun; Liu, Zhaomeng; Wang, Zhixing; Yan, Guochun; Li, Xinhai; Wang, Jiexi] Cent S Univ, Sch Met & Environm, 932 Lushan South Rd, Changsha 410083, Peoples R China.
[Shih, Kaimin; Wang, Jiexi] Univ Hong Kong, Dept Civil Engn, Hong Kong, Hong Kong, Peoples R China.
[Song, Liubin] Changsha Univ Sci & Technol, Sch Chem & Biol Engn, Changsha 410004, Hunan, Peoples R China.
通讯机构:
[Wang, Jiexi] C
Cent S Univ, Sch Met & Environm, 932 Lushan South Rd, Changsha 410083, Peoples R China.
语种:
英文
关键词:
Cathodes;Coated materials;Coatings;Electrochemical electrodes;Electrodes;Electrolytes;Lithium;Lithium alloys;Lithium compounds;Molybdenum compounds;Temperature;Cath-ode materials;Electrochemical performance;Electrode/electrolyte interfaces;Elevated temperature;High rate capability;Molybdenum disulfide;Morphological observations;Reversible specific capacity;Lithium-ion batteries
期刊:
Journal of Power Sources
ISSN:
0378-7753
年:
2016
卷:
315
期:
May 31
页码:
294-301
基金类别:
This work is supported by National Natural Science Foundation of China (Grant no. 51574287 , 21501015 ). We also thank the Advanced Research Center of CSU for performing HRTEM examination and EDS elemental mapping. Dr. Jiexi Wang appreciates the supporting from Bao Steel Education Foundation.
机构署名:
本校为其他机构
院系归属:
化学与生物工程学院
摘要:
To improve the electrochemical performance of LiVPO4F at room and elevated temperature focusing on the stability of LiVPO4F electrode/electrolyte interface, for the first time, MoS2 nanosheets are introduced to modify LiVPO4F/C composites. The coating of MoS2 layers on the surface of LiVPO4F/C nanoparticles is realized via a solution method followed by low-temperature calcination. Morphological observations present that the MoS2 sheets are homogeneously wrapped around the LiVPO4F/C particles. When employed as cathode materials for lithium ion batteries, the MoS2-modified LiVPO4F/C composites e...

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