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Na and Cl co-doping modified LiNi0.5Co0.2Mn0.3O2 as cathode for lithium-ion battery

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成果类型:
期刊论文
作者:
Song, Liubin;Zheng, Youhang;Kuang, Yinjie;Zhao, Tingting;Xia, Yubo;...
通讯作者:
Kuang, YJ
作者机构:
[Kuang, Yinjie; Xiang, Youtao; Zheng, Youhang; Xiao, Minzhi; Xiao, Zhongliang; Song, Liubin; Zhao, Tingting; Xia, Yubo] Changsha Univ Sci & Technol, Coll Chem & Chem Engn, Changsha 410114, Hunan, Peoples R China.
[Kuang, Yinjie; Xiao, Zhongliang; Song, Liubin; Zhao, Tingting] Changsha Univ Sci & Technol, Coll Chem & Chem Engn, Hunan Prov Key Lab Mat Protect Elect Power & Trans, Changsha 410114, Hunan, Peoples R China.
[Tang, Fuli] Changsha Res Inst Min & Met Co LTD, Testing Technol Co, Changsha, Hunan, Peoples R China.
通讯机构:
[Kuang, YJ ] C
Changsha Univ Sci & Technol, Coll Chem & Chem Engn, Changsha 410114, Hunan, Peoples R China.
Changsha Univ Sci & Technol, Coll Chem & Chem Engn, Hunan Prov Key Lab Mat Protect Elect Power & Trans, Changsha 410114, Hunan, Peoples R China.
语种:
英文
关键词:
LiNi0.5Co0.2Mn0.3O2;doping;first-principle calculation;lithium-ion battery
期刊:
Nanotechnology
ISSN:
0957-4484
年:
2023
卷:
34
期:
36
页码:
365702
基金类别:
National Natural Science Foundation of China [21501015, 21545010, 31527803, 51774051]; Natural Science Foundation of Hunan Province of China [2022JJ30604]; Graduate Research Innovation Project of Hunan Province [CX20210813]; Hunan Provincial Key Laboratory of Materials Protection for Electric Power [2022CL01]
机构署名:
本校为第一且通讯机构
院系归属:
化学与生物工程学院
摘要:
In recent years, ternary nickel-rich layered oxides have gradually replaced traditional binary cathode materials in the lithium-ion battery market due to their advantages of high energy density and environmental protection. However, their structural instability of cathode materials has seriously affected the cycle performance of the battery. In order to optimize the internal structure of LiNi0.5Co0.2Mn0.3O2 (NCM523), the modified LiNi0.5Co0.2Mn0.3O2 was prepared by in situ doping Na and Cl wet grinding solid phase method. After 80 cycles at 1 C, the capacity retention rate was 80.91%, which wa...

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