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Nucleation effect of alpha/beta compound nucleating agents based on 1,3,5-benzenetricarboxylic acid tris(cyclohexylamide) in isotactic polypropylene

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成果类型:
期刊论文
作者:
He, Juan;Zhang, Yue-Fei*;Ren, Xiao-Qiong;Li, Yan
通讯作者:
Zhang, Yue-Fei
作者机构:
[Zhang, Yue-Fei; Li, Yan; Ren, Xiao-Qiong; He, Juan] Changsha Univ Sci & Technol, Sch Chem & Biol Engn, Changsha 410114, Hunan, Peoples R China.
通讯机构:
[Zhang, Yue-Fei] C
Changsha Univ Sci & Technol, Sch Chem & Biol Engn, Changsha 410114, Hunan, Peoples R China.
语种:
英文
关键词:
Compound nucleating agents;1,3,5-Benzenetricarboxylic acid tris(cyclohexylamide);Isotactic polypropylene;Nucleation efficiency;Properties
期刊:
Polymer Bulletin
ISSN:
0170-0839
年:
2019
卷:
76
期:
11
页码:
5559-5575
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21376031]
机构署名:
本校为第一且通讯机构
院系归属:
化学与生物工程学院
摘要:
Three α/β compound nucleating agents based on 1,3,5-benzenetricarboxylic acid tris(cyclohexylamide) (BTA-99) were prepared by using β-nucleating agents aromatic diamides (TMB-5), dicarboxylic acid salts (CaPi) and rare earth compound (WBG-II), and nucleation effects of the nucleating agents in isotactic polypropylene (iPP) were investigated. The optimal ratio of BTA-99 to TMB-5, CaPi and WBG-II was 1:1, 4:1 and 2:3, respectively, and the crystallization peak temperatures of iPP nucleated with BTA-99/TMB-5, BTA-99/CaPi and BTA-99/WBG-II were ...

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