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The effects of Ti3C2 MXene additive on lithiation induced stress in silicon/graphite-based electrodes for lithium ion batteries

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成果类型:
期刊论文
作者:
Wang, Zhuo;Liu, Jishan;Chen, Kongyao;Wu, Xueling;Mi, Liwei*;...
通讯作者:
Mi, Liwei;Mao, Weiguo
作者机构:
[Mi, Liwei; Wu, Xueling; Wang, Zhuo; Liu, Jishan; Chen, Kongyao] Zhongyuan Univ Technol, Ctr Adv Mat Res, Sch Mat & Chem Engn, Zhengzhou 450007, Peoples R China.
[Mao, Weiguo] Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha 410114, Peoples R China.
通讯机构:
[Mi, Liwei] Z
[Mao, Weiguo] C
Zhongyuan Univ Technol, Ctr Adv Mat Res, Sch Mat & Chem Engn, Zhengzhou 450007, Peoples R China.
Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha 410114, Peoples R China.
语种:
英文
关键词:
mechano-electrochemistry;Ti3C2 MXene;lithiation induced stress;silicon;graphite-based electrode;lithium-ion battery
期刊:
Journal of Physics D: Applied Physics
ISSN:
0022-3727
年:
2022
卷:
55
期:
18
页码:
185501
基金类别:
Fundamental Research Funds of Zhongyuan University of Technology [K2020QN018, K2020QN008]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [11772287]; Natural Science Foundation of Henan Province [212300410318]
机构署名:
本校为通讯机构
院系归属:
材料科学与工程学院
摘要:
The lithiation induced stress in multilayer silicon/graphite-based electrodes for lithium ion batteries is evaluated analytically. Firstly, the silicon/graphite-based composite active layer is reinforced by Ti3C2 MXene, and the effects of Ti3C2 MXene additive on elastic modulus of the active layer are discussed based on the Halpin-Tsai empirical equation. Secondly, biaxial stresses in both bilayer and symmetric trilayer silicon/graphite-based electrodes are estimated by a mechano-electrochemical model, which is derived by imitating thermal expa...

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