The self-assembled monolayers (SAMs) of alkanethiols such as 1-dodecanethiol (DDT) on the surface of polycrystalline gold grain on quartz crystal microbalance (QCM) at room temperature and alkynethiols such as phenylethynyl thiol (PET) on the surface of Au(111)/mica under − 65 °C have been fabricated. A multimode scanning probe microscope (SPM) investigation for the first time reveals the formation of stripe domain of DDT SAMs together with roundish domain. This feature was not caused by an annealing treatment but might be induced by coexiste...