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3D meso/macroporous Ni3S2@Ni composite electrode for high-performance supercapacitor

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成果类型:
期刊论文
作者:
Chen, Shuguang*;Li, Yuhan;Wu, Baoxin;Wu, Zixu;Li, Fujin;...
通讯作者:
Chen, Shuguang
作者机构:
[Li, Fujin; Li, Haibin; Liu, Peng; Wu, Zixu; Wu, Baoxin; Li, Yuhan; Chen, Shuguang; Wu, Jianghong] Changsha Univ Sci & Technol, Sch Mat Sci & Engn, Changsha 410114, Hunan, Peoples R China.
通讯机构:
[Chen, Shuguang] C
Changsha Univ Sci & Technol, Sch Mat Sci & Engn, Changsha 410114, Hunan, Peoples R China.
语种:
英文
关键词:
Ni3S2;Sulfuration;Supercapacitor;Formation mechanism
期刊:
Electrochimica Acta
ISSN:
0013-4686
年:
2018
卷:
275
页码:
40-49
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51701022]
机构署名:
本校为第一且通讯机构
院系归属:
材料科学与工程学院
摘要:
Ni3S2@Ni composite electrode for supercapacitor is synthesized via a one-step solvothermal treatment of Ni foam at 120 degrees C, exhibiting a 3D meso/macroporous network structure. The structure contains Ni3S2 nanosheets with 15-20 nm in thickness and meso/macropores with an average pore size of 24.69 nm, and its formation is regulated through the slow release of S2- ions and the solid/liquid interfacial reactions in absolute ethanol. At a current density of 17.15 A g(-1), the composite electrode demonstrates a high specific capacitance of 945.71 F g(-1), and at various current densities belo...

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