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Atomic layer deposition of Al2O3 on LiNi0.68Co0.10Mn0.22O2 for enhanced electrochemical performance

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成果类型:
期刊论文
作者:
Chen, Yangyang;Wang, Mingshan;Chen, Junchen;Yang, Jun;Li, Zhuangzhi;...
通讯作者:
Li, Xing;Zheng, Jianming
作者机构:
[Li, Zhuangzhi; Li, Xing; Wang, Mingshan; Yang, Jun; Chen, Junchen; Chen, Yangyang; Huang, Yun] Southwest Petr Univ, Sch New Energy & Mat, Chengdu 610500, Sichuan, Peoples R China.
[Chen, Zhaoyong] Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha 410114, Peoples R China.
[Zheng, Jianming; Zou, Yue] Xiamen Univ, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China.
通讯机构:
[Li, Xing] S
[Zheng, Jianming] X
Southwest Petr Univ, Sch New Energy & Mat, Chengdu 610500, Sichuan, Peoples R China.
Xiamen Univ, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China.
语种:
英文
关键词:
Alumina;Aluminum oxide;Atomic layer deposition;Atoms;Cathode materials;Cathodes;Electrolytes;Lithium compounds;Manganese compounds;Microstructure;Nickel compounds;Passivation;Cycling stability;Electrochemical performance;Energy storage and conversions;High energy densities;Interfacial stabilities;Lithium ion diffusion;Passivation layer;Rate capabilities;Vanadium compounds
期刊:
Materials Letters
ISSN:
0167-577X
年:
2020
卷:
271
期:
Jul.15
页码:
127771
基金类别:
This work supported by Department of Science & Technology of Sichuan Province ( 2019-GH02-00052-HZ ).
机构署名:
本校为其他机构
院系归属:
材料科学与工程学院
摘要:
Although there have been many studies on atomic layer deposition of Al2O3 to improve the electrochemical performances of ternary cathode materials, few studies considered the harsh conditions such as high temperature and high voltage at the same time. In this work, the Al2O3 passivation layer is employed to coat the high nickel (Ni) LiNi0.68Co0.10Mn0.22O2 cathode through atomic layer deposition (ALD) approach. The Al2O3 coated LiNi0.68Co0.10Mn0.22O2 presents superior cycling stability and rate capability than the pristine at the cut-off voltage...

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