Based on inexpensive, safe, and environmentally friendly active redox species, neutral polysulfide-ferrocyanide redox flow batteries (PFRFBs) have attracted much attention for large-scale energy storage. However, the development of PFRFBs is undermined by the expensive commercial membrane materials as well as the sluggish polysulfide redox reactions. This work attempts to solve these critical problems by combining the economical membrane with the highly catalytic electrode. In specific, K+-exchanged sulfonated polyether ether ketone (SPEEK-K) m...