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Effects of chelating agents on electrochemical properties of Na0.9Ni0.45Mn0.55O2 cathode materials

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成果类型:
期刊论文
作者:
Liu, Zengsheng;Li, Lingjun*;Chen, Jie;Yang, Huiping;Xia, Lingfeng;...
通讯作者:
Li, Lingjun
作者机构:
[Chen, Jiaxin; Yang, Huiping; Xia, Lingfeng; Chen, Zhaoyong; Liu, Zengsheng; Chen, Jie; Li, Lingjun; Duan, Junfei] Changsha Univ Sci & Technol, Sch Mat Sci & Engn, Changsha 410004, Peoples R China.
[Li, Lingjun] Changsha Univ Sci & Technol, Sch Phys & Elect Sci, Changsha 410004, Peoples R China.
通讯机构:
[Li, Lingjun] C
Changsha Univ Sci & Technol, Sch Mat Sci & Engn, Changsha 410004, Peoples R China.
语种:
英文
关键词:
Amines;Cathode materials;Chelation;Citric acid;Electrochemical properties;Ethylene;Ethylenediaminetetraacetic acid;Manganese compounds;Metal ions;Nickel compounds;Sodium compounds;Sodium-ion batteries;Sol-gel process;Sol-gels;Complexing agents;Cycled electrode;Electrochemical performance;Interfacial stabilities;Layered cathode;Layered cathode materials;Molecular levels;Selection criteria;Cathodes
期刊:
Journal of Alloys and Compounds
ISSN:
0925-8388
年:
2021
卷:
855
页码:
157485
基金类别:
This work was financially supported by the National Natural Science Foundation of China (No. 51774051 ), The Science and Technology Planning Project of Hunan Province (No. 2019RS2034 ), The Changsha City Fund for Distinguished and Innovative Young Scholars ) (No. KQ1707014 ), The Hunan Provincial Natural Science Foundation of China (No. 2018JJ2428 ), Scientific Research Fund of Hunan Provincial Education Department .(No. 17B002 ). This work was financially supported by the National Natural Science Foundation of China (No. 51774051), The Science and Technology Planning Project of Hunan Province (No. 2019RS2034), The Changsha City Fund for Distinguished and Innovative Young Scholars) (No. KQ1707014), The Hunan Provincial Natural Science Foundation of China (No. 2018JJ2428), Scientific Research Fund of Hunan Provincial Education Department.(No. 17B002).
机构署名:
本校为第一且通讯机构
院系归属:
物理与电子科学学院
材料科学与工程学院
摘要:
The development of the layered cathode material for sodium ion batteries are hindered by synthesis approaches. The sol-gel method is a promising way to prepare the cathodes due to the advantage of mixing the raw product at atomic or molecular level, while the selection criteria for complexing agents are still unclear. Herein, the Na0.9Ni0.45Mn0.55O2 cathode is successfully prepared via sol-gel method, by using sucrose, glucose, citric acid, and ethylene diamine tetra-acetic acid as the chelating agent, respectively. The effects of different chelating agents on the morphologies, structural and ...

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