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Preparation and electrochemical properties of Ba0.8La0.2FeO3-δcathode for intermediate-temperature solid oxide fuel cells

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成果类型:
期刊论文
作者:
Liu, Peng*;Zhu, Hongze;Kong, Jiangrong;Wei, Ning;Wang, Can;...
通讯作者:
Liu, Peng
作者机构:
[Wei, Ning; Wang, Can; Liu, Qicheng; Liu, Peng; Yang, Xianfeng; Zhu, Hongze] Changsha Univ Sci & Technol, Sch Mat Sci & Engn, Changsha 410114, Hunan, Peoples R China.
[Kong, Jiangrong] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China.
通讯机构:
[Liu, Peng] C
Changsha Univ Sci & Technol, Sch Mat Sci & Engn, Changsha 410114, Hunan, Peoples R China.
语种:
英文
关键词:
Amino acids;Barium compounds;Catalyst activity;Cathodes;Electrochemical corrosion;Electrochemical properties;Electrodes;Electrolytes;Electrolytic reduction;Fuel cells;Gas fuel purification;Iron oxides;Lanthanum oxides;Nitrates;Phase interfaces;Doped barium ferrite;Electrochemical measurements;Glycine nitrate process;Intermediate temperature solid oxide fuel cell;Oxygen reduction reaction;Polarization resistances;Samarium doped ceria electrolytes;Self-propagating combustion;Solid oxide fuel cells (SOFC)
期刊:
Journal of Sol-Gel Science and Technology
ISSN:
0928-0707
年:
2017
卷:
82
期:
1
页码:
233-238
基金类别:
National Natural Science Foundation of China#&#&#21506259 National Natural Science Foundation of China#&#&#51572035 Natural Science Foundation of Hunan Province#&#&#2015JJ2012 National Natural Science Foundation of China#&#&#21276028
机构署名:
本校为第一且通讯机构
院系归属:
材料科学与工程学院
摘要:
Abstract: Perovskite Ba0.8La0.2FeO3-δ was synthesized via a glycine–nitrate process as the cathode material for intermediate-temperature solid oxide fuel cells. Ultra-fine pure phase Ba0.8La0.2FeO3-δ powder was obtained after the self-propagating combustion of a complex xerogel precursor. The Ba0.8La0.2FeO3-δ cathode showed good compatibility and an enhanced phase interface with a samarium-doped ceria electrolyte. Electrochemical measurements showed that the Ba0.8La0.2FeO3-δ cathode achieved a low polarization resistance of 0.58 Ω cm2 at ...

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