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Revealing the Mechano‐Electrochemical Coupling Behavior and Discharge Mechanism of Fluorinated Carbon Cathodes toward High‐Power Lithium Primary Batteries

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成果类型:
期刊论文
作者:
Luo, Zhenya;Luo, Shun;Yang, Mei;Mao, Weiguo;Dai, Cuiying;...
通讯作者:
Wu, Dazhuan;Ouyang, XP;Pan, Junan
作者机构:
[Wu, Dazhuan; Luo, Zhenya; Ouyang, Xiaoping] Zhejiang Univ, Coll Energy Engn, Hangzhou 310027, Zhejiang, Peoples R China.
[Luo, Zhenya; Pan, Junan; Yang, Mei; Pan, Yong; Luo, Shun; Ouyang, Xiaoping; Dai, Cuiying; Mao, Weiguo] Xiangtan Univ, Sch Mat Sci & Engn, Xiangtan 411105, Hunan, Peoples R China.
[Dai, Cuiying; Mao, Weiguo] Changsha Univ Sci & Technol, Sch Mat Sci & Engn, Changsha 410076, Hunan, Peoples R China.
通讯机构:
[Wu, DZ; Ouyang, XP ] Z
[Pan, JA] X
Zhejiang Univ, Coll Energy Engn, Hangzhou 310027, Zhejiang, Peoples R China.
Xiangtan Univ, Sch Mat Sci & Engn, Xiangtan 411105, Hunan, Peoples R China.
语种:
英文
关键词:
discharge mechanism;digital image correlation;fluorinated graphene nanosheets;mechano-electrochemical coupling;primary batteries
期刊:
Small
ISSN:
1613-6810
年:
2024
卷:
20
期:
7
页码:
2305980-
基金类别:
This work was financially supported by the Innovation Team of Hunan Province (Grant No. 2018RS3091), the National Natural Science Foundation of China (Grant No. 11902283), and the Scientific Research Foundation of Hunan Provincial Education Department (Gra [2018RS3091]; Innovation Team of Hunan Province [11902283]; National Natural Science Foundation of China [21B0126]; Scientific Research Foundation of Hunan Provincial Education Department
机构署名:
本校为其他机构
院系归属:
材料科学与工程学院
摘要:
The mechano‐electrochemical coupling behavior of a CFx cathode is investigated by in situ monitoring the dynamic evolution of strain/stress using a digital image correlation technique, electrochemical methods, and theoretical equations. The structure‐ and rate‐dependent mechano‐electrochemical coupling behaviors and discharge mechanisms of the CFx cathodes are investigated for the development of high‐power Li/CFx batteries. Abstract Unclear reaction mechanisms and unsatisfactory power performance hinder the further development of advanced ...

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