Strong interaction between efficient magnetic tri-metallic PdFeCo nano-alloy towards formic acid dehydrogenation and application of in-situ hydrogenation
National Natural Science Foundation of China [52206192, 22138002, 22178089]; Hunan Provincal Natural Science Foundation [2023JJ40015, 2022JJ40499]
机构署名：
本校为第一且通讯机构
院系归属：
能源与动力工程学院
摘要：
The mesoporous carbons with abundant Fe-Co sites were prepared through one-step carbonization of a MOF materials (ZIF-67) with sodium iron ethylenediaminetetraacetic acid [NaFe(III)EDTA], which can facilitate the nucleation and growth of highly dispersed palladium active sites. The robust synergistic interaction between Pd and FeCo metal with moderate work functions is responsible for the enhanced catalytic activity. Interfacing Pd nano-particles with FeCo sites has been demonstrated for the first time to boost the heterogeneous catalysis of hydrogen production from formic acid, affording the ...
