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Crystallization kinetics of isotactic polypropylene nucleated with octamethylenedicarboxylic dibenzoylhydrazide under isothermal and non-isothermal conditions

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成果类型:
期刊论文
作者:
Zhou, Pei-Zhang;Zhang, Yue-Fei*;Lin, Xiang-Feng
通讯作者:
Zhang, Yue-Fei
作者机构:
[Lin, Xiang-Feng; Zhang, Yue-Fei; Zhou, Pei-Zhang] Changsha Univ Sci & Technol, Sch Chem & Biol Engn, 960 South Wanjiali Rd, Changsha 410114, Hunan, Peoples R China.
通讯机构:
[Zhang, Yue-Fei] C
Changsha Univ Sci & Technol, Sch Chem & Biol Engn, 960 South Wanjiali Rd, Changsha 410114, Hunan, Peoples R China.
语种:
英文
关键词:
Crystallization kinetics;Isotactic polypropylene;Nucleating agent;Octamethylenedicarboxylic dibenzoylhydrazide
期刊:
Journal of Thermal Analysis and Calorimetry
ISSN:
1388-6150
年:
2019
卷:
136
期:
2
页码:
749-757
基金类别:
Acknowledgements The authors are grateful to National Natural Science Foundation of China (Grant No. 21376031) and Scientific Research Fund of Hunan Provincial Education Department (Grant No. 16A004) for financial supports.
机构署名:
本校为第一且通讯机构
院系归属:
化学与生物工程学院
摘要:
Octamethylenedicarboxylic dibenzoylhydrazide (TMC-300) was used as a nucleating agent for isotactic polypropylene (iPP) for the first time. The Avrami method and the Caze method were used to analyze the isothermal and non-isothermal crystallization kinetics of iPP incorporated with TMC-300, respectively. During isothermal crystallization, the half crystallization time at 130°C reduces from 130s of virgin iPP to 44s after addition of TMC-300, which reflects that TMC-300 increased the crystallization rate of iPP obviously. The crystallization ac...

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