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Rational Molecular Design Strategy of a Carbonyl Cathode for Better Aluminum Organic Batteries

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成果类型:
期刊论文
作者:
Luo, Wenbin*;Liu, Yanhui;Zhang, Zhen;Li, Fenghong;Chao, Zisheng;...
通讯作者:
Luo, Wenbin;Chao, ZS
作者机构:
[Fan, JinCheng; Liu, Yanhui; Chao, Zisheng; Luo, Wenbin; Luo, WB; Chao, ZS; Zhang, Zhen; Li, Fenghong] Changsha Univ Sci & Technol, Sch Mat Sci & Engn, Changsha 410114, Hunan, Peoples R China.
通讯机构:
[Luo, WB; Chao, ZS ] C
Changsha Univ Sci & Technol, Sch Mat Sci & Engn, Changsha 410114, Hunan, Peoples R China.
语种:
英文
关键词:
aluminum batteries;organic cathode;molecular design;sulfurization;density functional theory
期刊:
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
ISSN:
2168-0485
年:
2023
卷:
11
期:
31
页码:
11406-11414
基金类别:
National Natural Science Foundation of China [51304052]; Doctoral Program of Higher Education of China [20133514120002]; Foundation of Hunan Provincial Department of Education for Outstanding Young Scholars [18B163]; Natural Science Foundation of Changsha City [kq2202195]
机构署名:
本校为第一且通讯机构
院系归属:
材料科学与工程学院
摘要:
Thispaper reports SPTCDA cathode for green and sustainablealuminum organic battery. Aluminumbatteries with aluminum as the anode and organic materialsas the cathode have continuously drawn considerable attention becauseof their high theoretical energy density, natural abundance, and environmentallybenign nature. Herein, we have done an elaborate design work on thebasis of & pi;-& pi; conjugated organic molecule PTCDAby a molecular engineering strategy. Introducing a sulfur atom toreplace the H atom in the aromatic ring of the PTCDA molecule to formSPTCDA (sulfurized PTCDA) with p-& pi; conjuga...

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