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Air-stabilized pore structure engineering of antimony-based anode by electrospinning for potassium ion batteries

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成果类型:
期刊论文
作者:
Qian, Miaomiao;Zhang, Wenzhe;Luo, Gang;Wu, Chun;Qin, Wei*
通讯作者:
Qin, Wei
作者机构:
[Luo, Gang; Qian, Miaomiao; Wu, Chun; Zhang, Wenzhe; Qin, Wei] Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha 410114, Peoples R China.
通讯机构:
[Qin, Wei] C
College of Materials Science and Engineering, Changsha University of Science and Technology, Changsha 410114, China. Electronic address:
语种:
英文
关键词:
Anode material;Electrospinning;Porous structure, Antimony;Potassium-ion batteries
期刊:
Journal of Colloid and Interface Science
ISSN:
0021-9797
年:
2023
卷:
633
页码:
352-361
基金类别:
In summary, taking advantage of the different decomposition processes of PAN and PVP, we successfully prepared Sb2O3-modified carbonaceous fibres with porous structures by electrospinning and subsequent heat treatment in air and systematically studied the effect of annealing atmospheres. Influenced by the structure and chemical composition, the PIBs with the Sb2O3@PCN electrode prepared at the optimal ratio of PAN and PVP exhibit a reversible specific capacity of 437.3 mAh g-1 at a current
机构署名:
本校为第一机构
院系归属:
材料科学与工程学院
摘要:
Due to the large ionic radius and associated slow reaction kinetics of potassium ions, it is a major chal-lenge to find suitable anode materials for potassium-ion batteries. Herein, we design porous antimony -based nanofibres via a simple, low-cost and large scalable method to promote the electrochemical per-formance of potassium-ion batteries. Unlike those traditionally treated in inert atmospheres, using the different decomposition processes of polyacrylonitrile and polyvinylpyrrolidone in air, we obtain anti-mony trioxide embedded in porous carbon nanofibres (Sb2O3@PCN). The porous structur...

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