Layered material TaS2 hosts multiple structural phases and exotic correlated quantum states, including charge density wave (CDW), superconductivity, quantum spin liquid, and Mott insulating state. Here, we synthesized TaS2 monolayers in H and T phases using the molecular beam epitaxial (MBE) method and studied their electronic structures via angle-resolved photo-emission spectroscopy (ARPES). We found that the H phase TaS2 (H-TaS2) monolayer is metallic, with an energy band crossing the Fermi level. In contrast, the T phase TaS2 (T-TaS2) monolayer shows an insulated energy gap at the Fermi lev...