In this paper, the corrosion mechanism and tensile properties of basalt fibers in sodium hydroxide (NaOH) solution with various concentrations and temperatures were studied. The hydroxyl ions disrupt the -Si-O-Si- and -Si-O-Al- bonds leading to the formation of insoluble hydroxides. With the continuation of the hydration reaction, a hydration layer (corrosion shell) with high content of calcium, iron, manganese and titanium ions was formed on the fiber surface. The corrosion shell enabled an increase in the strength and elongation at break of b...