Plastic Deformation of LiNi 0.5 Mn 1.5 O 4 Single Crystals Caused by Domain Orientation Dynamics

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成果类型：

期刊论文

作者：

Nikita Vostrov;Isaac Martens;Mattia Colalongo;Edoardo Zatterin;Michal Ronovsky;...

通讯作者：

Marie-Ingrid Richard<&wdkj&>Tobias Schulli

作者机构：

[Michal Ronovsky] Univ. Grenoble Alpes, CNRS, Grenoble INP, LEPMI, Saint Martin d'Hères, 38402 France

[Adrien Boulineau] Univ. Grenoble Alpes, CEA, Liten, Grenoble, 38000 France

[Xiaobo Zhu] College of Materials Science and Engineering, Changsha University of Science and Technology, Changsha, 410114 China

[Nikita Vostrov; Isaac Martens; Mattia Colalongo; Edoardo Zatterin; Steven Leake; Tobias Schulli] ESRF - The European Synchrotron, 71 Avenue des Martyrs, Grenoble, 38000 France

Univ. Grenoble Alpes, CEA Grenoble, IRIG, MEM, NRX, 17 rue des Martyrs, Grenoble, 38000 France

通讯机构：

[Marie-Ingrid Richard; Tobias Schulli] E

ESRF - The European Synchrotron, 71 Avenue des Martyrs, Grenoble, 38000 France<&wdkj&>Univ. Grenoble Alpes, CEA Grenoble, IRIG, MEM, NRX, 17 rue des Martyrs, Grenoble, 38000 France<&wdkj&>ESRF - The European Synchrotron, 71 Avenue des Martyrs, Grenoble, 38000 France

语种：

英文

关键词：

high voltage cathode;Li-ion batteries;LMNO;spinel;SXDM

期刊：

Advanced Energy Materials

ISSN：

1614-6832

年：

2025

页码：

2404933

DOI：

10.1002/aenm.202404933

机构署名：

本校为其他机构

院系归属：

材料科学与工程学院

摘要：

The nanoscale mechanisms of ion deintercalation in battery cathode materials remain poorly understood, especially the relationship between crystallographic defects (dislocations, small angle grain boundaries, vacancies, etc ), device performance, and durability. In this work, operando scanning X-ray diffraction microscopy (SXDM) and multi-crystal X-ray diffraction (MCXD) are used to investigate microstrain and lattice tilt inhomogeneities inside Li 1 − x Ni 0.5 Mn 1.5 O 4 cathode particles during electrochemical cycling and their influence on ...

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Plastic Deformation of LiNi 0.5 Mn 1.5 O 4 Single Crystals Caused by Domain Orientation Dynamics

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