A non-topotactic redox reaction enabled K2V3O8 as a high voltage cathode material for potassium-ion batteries

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成果类型：

期刊论文

作者：

Yang, Yusi;Liu, Zhifeng;Deng, Leqing;Tan, Lulu;Niu, Xiaogang;...

通讯作者：

Zhu, Zhiping;Zhu, Yujie

作者机构：

[Liu, Zhifeng; Zhu, Zhiping; Yang, Yusi] Changsha Univ Sci & Technol, Sch Chem & Biol Engn, Changsha 410114, Hunan, Peoples R China.

[Niu, Xiaogang; Tan, Lulu; Deng, Leqing; Zhu, Yujie] Beihang Univ, Sch Chem, Beijing 100191, Peoples R China.

[Sanad, Mustafa M. S.] Cent Met R & D Inst CMRDI, Chem & Electroproc Dept, Cairo, Egypt.

[Zeng, Liang] Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn, Sch Chem Engn & Technol, Key Lab Green Chem Technol,Minist Educ, Tianjin 300072, Peoples R China.

[Zhu, Yujie] Beihang Univ, Beijing Adv Innovat Ctr Biomed Engn, Beijing 100191, Peoples R China.

通讯机构：

[Zhu, Zhiping] C

[Zhu, Yujie] B

Changsha Univ Sci & Technol, Sch Chem & Biol Engn, Changsha 410114, Hunan, Peoples R China.

Beihang Univ, Sch Chem, Beijing 100191, Peoples R China.

Beihang Univ, Beijing Adv Innovat Ctr Biomed Engn, Beijing 100191, Peoples R China.

语种：

英文

期刊：

Chemical Communications

ISSN：

1359-7345

年：

2019

卷：

期：

页码：

14988-14991

DOI：

10.1039/c9cc07996c

基金类别：

"Top-notch Talents'' program of Beihang University; "Thousand Youth Talents Plan'' of China; National Natural Science Foundation of ChinaNational Natural Science Foundation of China [51902014, U1663224]; School of Chemical and Biological Engineering in the Changsha University of Science Technology

机构署名：

本校为第一且通讯机构

院系归属：

化学与生物工程学院

摘要：

When tested as the cathode material for potassium-ion batteries, K2V3O8 delivers a highly reversible capacity of over 100 mA h g-1 in the voltage range of 1.5-4.5 V with 73% capacity retained after 50 cycles. Charge-discharge is achieved by a nontopotactic process between K2V3O8 and KV3O8 (DeltaV approximately -2...

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A non-topotactic redox reaction enabled K2V3O8 as a high voltage cathode material for potassium-ion batteries

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