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A selective artemisinin-sensor using metalloporphyrin as a recognition element entrapped in the Au-nanoparticles-chitosan modified electrodes

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成果类型:
期刊论文
作者:
Gong, Fu-Chun*;Xiao, Zi-Dan;Cao, Zhong;Wu, Dao-Xin
通讯作者:
Gong, Fu-Chun
作者机构:
[Xiao, Zi-Dan; Cao, Zhong; Gong, Fu-Chun; Wu, Dao-Xin; Gong, FC] Changsha Univ Sci & Technol, Coll Chem & Environm Engn, Changsha 410076, Peoples R China.
通讯机构:
[Gong, Fu-Chun] C
Changsha Univ Sci & Technol, Coll Chem & Environm Engn, Changsha 410076, Peoples R China.
语种:
英文
关键词:
artemisinin sensor;supramolecular recognition;metalloporphyrin;Au-nanoparticles-chitosan
期刊:
Talanta
ISSN:
0039-9140
年:
2007
卷:
72
期:
4
页码:
1453-1457
机构署名:
本校为第一且通讯机构
院系归属:
化学与生物工程学院
摘要:
An amperometric artemisinin (ARN) sensor based on the supramolecular recognition of glycosylated metalloporphyrin, which is included in the Au-nanoparticles-chitosan film coated on the glass carbon electrodes, was developed. For the improvement of the selectivity of artemisinin detection, 5,10,15,20-tetrakis[2-(2,3,4,6-tetraacetyl-β-d-glucopyranosyl)-1-O-phenyl]porphyrin (T(o-glu)PPH) metal complex [FeT(o-glu)PPCl] was synthesized and employed as a ARN-sensitive and -selective material in the amperometric sensors. The proposed [FeT(o-glu)PPCl]/Au-nanoparticles modified electrodes showed e...

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