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Prolonging the Cycle Life of a Lithium-Air Battery by Alleviating Electrolyte Degradation with a Ceramic-Carbon Composite Cathode.

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成果类型:
期刊论文
作者:
Luo, Zhifu;Li, Yanyan;Liu, Zixuan*;Pan, Linhai;Guan, Wanbing;...
通讯作者:
Liu, Zixuan;Wang, Deyu;Liu, Peng
作者机构:
[Guan, Wanbing; Li, Yanyan; Luo, Zhifu; Pan, Linhai; Wang, Deyu; Liu, Zixuan; Wang, DY] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Dept New Energy Technol, Ningbo 315201, Zhejiang, Peoples R China.
[Luo, Zhifu] Univ Chinese Acad Sci, Beijing 100049, Peoples R China.
[Liu, Peng] Changsha Univ Sci & Technol, Sch Mat Sci & Engn, Changsha 410114, Hunan, Peoples R China.
通讯机构:
[Liu, ZX; Wang, DY; Liu, Peng] C
Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Dept New Energy Technol, Ningbo 315201, Zhejiang, Peoples R China.
Changsha Univ Sci & Technol, Sch Mat Sci & Engn, Changsha 410114, Hunan, Peoples R China.
语种:
英文
关键词:
carbon;ceramics;electrochemistry;lithium;surface analysis
期刊:
ChemSusChem
ISSN:
1864-5631
年:
2019
卷:
12
期:
22
页码:
4962-4967
基金类别:
This work was financially supported by the National Natural Science Foundation of China (grant no. 51602321) and Ningbo S&T Innovation 2025 Major Special Programme (grant no. 2018B10061).
机构署名:
本校为通讯机构
院系归属:
材料科学与工程学院
摘要:
Carbon materials with a high specific surface area are usually preferred to construct the air cathode of lithium-air batteries due to their abundant sites for oxygen reduction and discharge product growth. However, the high surface area also amplifies electrolyte degradation during charging, which would become the threshold of cyclability after addressing the issue of electrode passivation and pore clogging, but is usually overlooked in relevant research. Herein, it is proven that the critical influence of cathode surface area on electrolyte consumption by adopting carbon-ceramic composites to...

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