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Multiple Anionic Transition-Metal Oxycarbide for Better Lithium Storage and Facilitated Multielectron Reactions

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成果类型:
期刊论文
作者:
Cuan, Jing;Zhou, You;Zhang, Jian;Zhou, Tengfei;Liang, Gemeng;...
通讯作者:
Guo, Zaiping;Yu, Xuebin
作者机构:
[Cuan, Jing; Guo, Zaiping; Liang, Gemeng; Zhou, Tengfei; Pang, Wei Kong] Univ Wollongong, Inst Superconducting & Elect Mat, Wollongong, NSW 2511, Australia.
[Guo, Zaiping] Univ Wollongong, Sch Mech Mat & Mechatron Engn, Wollongong, NSW 2511, Australia.
[Yu, Xuebin] Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China.
[Zhou, You] Ningbo Univ, Fac Mat Sci & Chem Engn, Ningbo 315211, Zhejiang, Peoples R China.
[Zhang, Jian] Changsha Univ Sci & Technol, Coll Automot & Mech Engn, Changsha 410015, Hunan, Peoples R China.
通讯机构:
[Guo, Zaiping] U
[Yu, Xuebin] F
Univ Wollongong, Inst Superconducting & Elect Mat, Wollongong, NSW 2511, Australia.
Univ Wollongong, Sch Mech Mat & Mechatron Engn, Wollongong, NSW 2511, Australia.
Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China.
语种:
英文
关键词:
oxycarbide configurations;anion-centered chemistry;multielectron reactions;interface integrations;lithium ion batteries
期刊:
ACS Nano
ISSN:
1936-0851
年:
2019
卷:
13
期:
10
页码:
11665-11675
基金类别:
This work was partially supported by the National Science Fund for Distinguished Young Scholars (Grant No. 51625102) the National Natural Science Foundation of China (Grant Nos. 51471053 and 51802357), the Science and Technology Commission of Shanghai Municipality (Grant No. 17XD1400700), Hubei Provincial Natural Science Foundation of China (2018CFB237), and the Fundamental Research Funds for the Central Universities (CZT19003) and are gratefully acknowledged. Also financial support provided by the Australian Research Council (ARC) (Grant Nos. LP160101629, DE190100504, and FT150100109) is gratefully acknowledged. The authors thank the Electron Microscopy Centre (EMC) at the University of Wollongong. The authors also thank Dr. T. Silver and Dr. J. Knott for critical reading of the manuscript. The authors also thank Dr. Y. Zheng for his help in assembling the batteries for operando synchrotron X-ray powder diffraction test. Part of this research was undertaken on the Powder Diffraction beamline at the Australian Synchrotron Victoria, Australia.
机构署名:
本校为其他机构
院系归属:
汽车与机械工程学院
摘要:
As an important class of multielectron reaction materials, the applications of transition-metal oxides (TMOs) are impeded by volume expansion and poor electrochemical activity. To address these intrinsic limitations, the renewal of TMOs inspires research on incorporating an advanced interface layer with multiple anionic characteristics, which may add functionality to support properties inaccessible to a single-anion TMO electrode. Herein, a transition-metal oxycarbide (TMOC, M = Mo) with more than one anionic species was prepared as an interfac...

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