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New Insight into the Confinement Effect of Microporous Carbon in Li/Se Battery Chemistry: A Cathode with Enhanced Conductivity

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成果类型:
期刊论文
作者:
Wang, Xiwen;Tan, Yuqing;Liu, Zhixiao;Fan, Yuqin;Li, Mingnan;...
通讯作者:
Zhang, Shiguo
作者机构:
[Liu, Zhixiao; Tan, Yuqing; Wang, Xiwen; Fan, Yuqin; Li, Mingnan; Younus, Hussein A.; Zhang, Shiguo] Hunan Univ, Coll Mat Sci & Engn, State Key Lab Adv Design & Mfg Vehicle Body, Tianma Rd 27, Changsha 410082, Hunan, Peoples R China.
[Duan, Junfei] Changsha Univ Sci & Technol, Sch Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China.
[Deng, Huiqiu] Hunan Univ, Sch Phys & Elect, Changsha 410082, Hunan, Peoples R China.
通讯机构:
[Zhang, Shiguo] H
Hunan Univ, Coll Mat Sci & Engn, State Key Lab Adv Design & Mfg Vehicle Body, Tianma Rd 27, Changsha 410082, Hunan, Peoples R China.
语种:
英文
关键词:
conductivity;confined Se cathodes;electrolytes;lithium-selenium batteries
期刊:
Small
ISSN:
1613-6810
年:
2020
卷:
16
期:
17
页码:
2000266-
基金类别:
X.W., Y.T., and Z.L. contributed equally to this work. The authors are grateful to National Natural Science Foundation of China (Grant Nos. 51772089, 21872046, 51802092, and 51904098), Youth 1000 Talent Program of China, Fundamental Research Funds for the Central Universities, Outstanding Youth Scientist Foundation of Hunan Province (Grant No. 2018JJ1009), Natural Science Foundation of Hunan Province (Grant No. 2019JJ50050) and Provincial Science and Technology Innovation Platform and Talent Plan-Changsha, Zhuzhou and Xiangtan High-level Talents Accumulation Project (Grant No. 2017XK2023), and the Research and Development Plan of Key Areas in Hunan Province (Grant No. 2019GK2235).
机构署名:
本校为其他机构
院系归属:
材料科学与工程学院
摘要:
Embedding the fragmented selenium into the micropores of carbon host has been regarded as an effective strategy to change the Li–Se chemistry by a solid–solid mechanism, thereby enabling an excellent cycling stability in Li–Se batteries using carbonate electrolyte. However, the effect of spatial confinement by micropores in the electrochemical behavior of carbon/selenium materials remains ambiguous. A comparative study of using both microporous (MiC) and mesoporous carbons (MeC) with narrow pore size distribution as selenium hosts is herein ...

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