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High Performance and Structural Stability of K and Cl Co-Doped LiNi0.5Co0.2Mn0.3O2 Cathode Materials in 4.6 Voltage.

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成果类型:
期刊论文
作者:
Chen, Zhaoyong;Gong, Xiaolong;Zhu, Huali;Cao, Kaifeng;Liu, Qiming;...
通讯作者:
Chen, ZY
作者机构:
[Duan, Junfei; Chen, Zhaoyong; Gong, Xiaolong; Cao, Kaifeng; Liu, Qiming; Liu, Jun; Li, Lingjun] Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha, Hunan, Peoples R China.
[Zhu, Huali] Changsha Univ Sci & Technol, Coll Phys & Elect Sci, Changsha, Hunan, Peoples R China.
[Zhu, Huali] Univ New Hampshire, Dept Chem, Durham, NH 03824 USA.
通讯机构:
[Chen, ZY ]
Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha, Hunan, Peoples R China.
语种:
英文
关键词:
LiNi0.5Co0.2Mn0.3O2;cation mixing;co-doping;lithium ion batteries;phase transition
期刊:
FRONTIERS IN CHEMISTRY
ISSN:
2296-2646
年:
2019
卷:
6
期:
JAN
页码:
643
基金类别:
We thank the financial support from Project funded by the National Natural Science Foundation of China (Grant No. 51604042, 51874048 and 21601020), the Research Foundation of Education Bureau of Hunan Province (Grant No. 16A001), and Science and Technology PlanChangsha (Grant No. kq1701076).
机构署名:
本校为第一且通讯机构
院系归属:
物理与电子科学学院
材料科学与工程学院
摘要:
The high energy density lithium ion batteries are being pursued because of their extensive application in electric vehicles with a large mileage and storage energy station with a long life. So, increasing the charge voltage becomes a strategy to improve the energy density. But it brings some harmful to the structural stability. In order to find the equilibrium between capacity and structure stability, the K and Cl co-doped LiNi0.5Co0.2Mn0.3O2 (NCM) cathode materials are designed based on defect theory, and prepared by solid state reaction. The structure is investigated by means of X-ray diffra...

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