Aluminum-lithium (Al–Li) alloys have become an essential material for aircraft skin in the aerospace industry owing to their high strength and low density. An optimized coherent Cu/Li ratio and well controlled precipitation sequence are critical to upgrade the desired properties. In this study, we systematically evaluate the effect of the Cu/Li ratio (ranging from 0.5 to 1.4) on the aging hardening and precipitation behavior of Al–Cu–Li alloys with specific rare earth elements (Sc, Zr, and Ce). Using state-of-the-art aberration-corrected tra...