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Interface interaction of Ag-CeO2-Co3O4 facilitate ORR/OER activity for Zn-air battery

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成果类型:
期刊论文
作者:
Li, Tao;He, Zhanglong;Liu, Xiang;Jiang, Min;Liao, Qin;...
通讯作者:
Hao He
作者机构:
[He, Hao; He, Zhanglong; Liu, Xiang; Zhao, Chen; Li, Tao; Ding, Ruida; Zhang, Shanshan; Liao, Qin; Liu, Shan; Guo, Weibin] Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha, Peoples R China.
[Jiang, Min] Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, Shanghai, Peoples R China.
通讯机构:
[Hao He] C
College of Materials Science and Engineering, Changsha University of Science & Technology, China
语种:
英文
关键词:
Interface Interaction;ORR/OER dual -functional electrocatalyst;Zinc -air battery
期刊:
Surfaces and Interfaces
ISSN:
2468-0230
年:
2022
卷:
33
页码:
102270
机构署名:
本校为第一机构
院系归属:
材料科学与工程学院
摘要:
Developing a highly stable and high-efficiency catalyst for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is critical to developing Zinc-air battery. In this work, a facile strategy was applied to prepared Ag-CeO2-Co3O4/C dual-functional catalyst. The interface interaction affecting the electronic structure and valence state of Ag, Ce and Co, significantly facilitates the ORR/OER catalytic activity. For the Ag-CeO2-Co3O4/C catalyst, the half-wave potential is 0.80 V and limiting current density is 6.2 mA cm(-2) in ORR, while the overpotential is 340 mV s(-1) at 10 mA cm(-...

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