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Donor-acceptor mixed-ligand MOF with energy transfer-mediated high-efficiency singlet oxygen generation for boosted organic photosynthesis

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成果类型:
期刊论文
作者:
Jin, Hong-Guang*;Lin, Wei;Zhao, Peng-Cheng;Deng, Jie;Liu, Yi;...
通讯作者:
Jin, Hong-Guang;Gu, Zhi-Gang
作者机构:
[Jin, Hong-Guang] School of Materials Science and Engineering, Changsha University of Science & Technology, Changsha 410114, China. Electronic address: jesonjin08@csust.edu.cn
[Chao, Zi-Sheng; Liu, Yi; Deng, Jie; Lin, Wei; Zhao, Peng-Cheng] School of Materials Science and Engineering, Changsha University of Science & Technology, Changsha 410114, China
[Gu, Zhi-Gang] Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, Fujian 350108, China
[Gu, Zhi-Gang] State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[Gu, Zhi-Gang] University of Chinese Academy of Sciences, Beijing 100049, China. Electronic address: zggu@fjirsm.ac.cn
通讯机构:
[Hong-Guang Jin] S
[Zhi-Gang Gu] F
School of Materials Science and Engineering, Changsha University of Science & Technology, Changsha 410114, China<&wdkj&>Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, Fujian 350108, China<&wdkj&>State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China<&wdkj&>University of Chinese Academy of Sciences, Beijing 100049, China
语种:
英文
关键词:
Energy transfer;Metal-organic framework;Photocatalytic oxidation;Singlet oxygen
期刊:
Journal of Colloid and Interface Science
ISSN:
0021-9797
年:
2025
卷:
689
页码:
137231
基金类别:
CRediT authorship contribution statement Hong-Guang Jin: Writing – review & editing, Writing – original draft, Supervision, acquisition, Conceptualization. Wei Lin: Writing – original draft, Investigation, Data curation. Peng-Cheng Zhao: Investigation, Data curation. Jie Deng: Investigation. Yi Liu: Data curation. Zhi-Gang Gu: Validation, Conceptualization. Zi-Sheng Chao: Supervision, Conceptualization.
机构署名:
本校为第一且通讯机构
院系归属:
材料科学与工程学院
摘要:
Integrating energy donor and acceptor chromophores as ligands within one MOF for advanced artificial photosynthesis is of great interest but appears to be a major challenge. Herein, via a simple one-pot synthetic strategy, an energy acceptor porphyrin ligand 5,15-di( p -benzoato)porphyrin (H 2 DPBP) was successfully integrated into an energy donor 1,4-naphthalenedicarboxylic acid (H 2 NDC)-based MOF (UiO-66-NDC) to construct a mixed-ligand MOF, donated as UiO-66-NDC-H 2 DPBP. Benefiting from the ample overlap between the emission spectrum of H 2 NDC and the absorption spectrum of H 2 DPBP, an ...

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