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An efficient strategy for sensing pyrophosphate based on nitrogen-rich quantum dots combined with graphene oxide

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成果类型:
期刊论文
作者:
Zou, Wu;Gong, Fuchun*;Gu, Tingting;Cao, Zhong;Xia, Jiaoyun
通讯作者:
Gong, Fuchun
作者机构:
[Gong, Fuchun; Gu, Tingting; Zou, Wu; Cao, Zhong; Xia, Jiaoyun] Changsha Univ Sci & Technol, Coll Chem & Biol Engn, Changsha 410114, Hunan, Peoples R China.
[Cao, Zhong] Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410114, Hunan, Peoples R China.
通讯机构:
[Gong, Fuchun] C
Changsha Univ Sci & Technol, Coll Chem & Biol Engn, Changsha 410114, Hunan, Peoples R China.
语种:
英文
关键词:
Nitrogen-rich quantum dots;Synthesis;Nanosensors;Pyrophosphate detection
期刊:
Microchemical Journal
ISSN:
0026-265X
年:
2018
卷:
141
页码:
466-472
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [31527803, 21545010]; Natural Science Foundation of State Key Laboratory of Life Organic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences [SKLBNPC17344]
机构署名:
本校为第一且通讯机构
院系归属:
化学与生物工程学院
摘要:
A facile approach was developed to prepare fluorescent nitrogen-rich quantum dots (NCQDs) using 2-azidoimidazole and ammonium hydroxide as reactants. The nitrogen and carbon elements of NCQDs form the frameworks of their nanostructures together and bear multiple active sites. By using NCQDs as fluorophores and graphene oxide (GO) as controllers, a hydrogen binding-based nanosensor was constructed for the detection of pyrophosphate (PPi). In NCQDs-GO sensing assemblies, the binding of GO to NCQDs results in the fluorescence quenching by FRET mechanism; while the addition of PPi leads to the flu...

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