O3-type layered oxides are widely investigated as cathodes for Na-ion batteries (SIBs) due to their high theoretical capacities and splendid initial Coulombic efficiency. However, they suffer from fast capacity fading owing to the complicated phase transformations, especially in high cut-off voltage (>4 V). Herein, Ti and Co elements were simultaneously introduced to O3-Na(Ni0.3Fe0.2Mn0.5)(0.85)Ti0.1Co0.05O2 (NFMTC) cathode material, and the effects of Ti/Co co-doping on phase structure and electrochemical properties were analyzed in detail. The results reveal that Ti/Co co-doping can enhance ...