Self-grown NiCuOx hybrids on a porous NiCuC substrate as an HER cathode in alkaline solution

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期刊论文

作者：

Yu, Linping;Dang, Yanliu;Zeng, Julan;He, Junkai;Murphy, Steven C.;...

通讯作者：

Suib, Steven L.;Zhang, Jian;Dou, Yuhai

作者机构：

[Yu, Linping; Zeng, Julan] Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410114, Peoples R China.

[Kerns, Peter; Yu, Linping; He, Junkai; Murphy, Steven C.; Dang, Yanliu; Suib, Steven L.] Univ Connecticut, Dept Chem, U-3060,55 North Eagleville Rd, Storrs, CT 06269 USA.

[Zhang, Jian] Changsha Univ Sci & Technol, Coll Automot & Mech Engn, Changsha 410114, Peoples R China.

[Dou, Yuhai] Griffith Univ, Ctr Clean Environm & Energy, Gold Coast 4222, Australia.

通讯机构：

[Suib, Steven L.] U

[Zhang, Jian] C

[Dou, Yuhai] G

Univ Connecticut, Dept Chem, U-3060,55 North Eagleville Rd, Storrs, CT 06269 USA.

Changsha Univ Sci & Technol, Coll Automot & Mech Engn, Changsha 410114, Peoples R China.

语种：

英文

关键词：

Electrocatalyst;Hydrogen evolution reaction;NiCuC substrate;NiCuOx hybrids

期刊：

Applied Surface Science

ISSN：

0169-4332

年：

2020

卷：

515

页码：

146117

DOI：

10.1016/j.apsusc.2020.146117

基金类别：

National Natural Science Foundation of ChinaNational Natural Science Foundation of China [51701023, 51874049]; Scientific Research Fund of Hunan Provincial Education DepartmentHunan Provincial Education Department [16C0026]; Natural Science Foundation of Hunan ProvinceNatural Science Foundation of Hunan Province [2017JJ1026]; Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation [2016CL04]; Changsha University of Science & Technology, P. R. China; US Department of Energy, Office of Basic Energy Sciences, Division of Chemical, Biological and Geological SciencesUnited States Department of Energy (DOE) [DE-FG02-86ER13622.A000]

机构署名：

本校为第一且通讯机构

院系归属：

汽车与机械工程学院

化学与生物工程学院

摘要：

Electrocatalysts converted directly from the substrates hold the key to achieve high catalytic activity and durability due to their high bonding strength, intimate electronic contact, and tunable phase composition. Herein, an electrically conductive porous NiCuC substrate was adopted to develop a multi-porous NiCuOx/NiCuC hydrogen evolution reaction (HER) catalyst using a one-step oxidation method in this research. The NiCuOx hybrids were characterized as three typical layers: an outer layer with NiCuO2 solid solution phase, a partially oxidize...

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Self-grown NiCuOx hybrids on a porous NiCuC substrate as an HER cathode in alkaline solution

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