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Modification research of LiAlO2-coated LiNi0.8Co0.1Mn0.1O2 as a cathode material for lithium-ion battery

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成果类型:
期刊论文
作者:
Xiao, Zhongliang;Hu, Chaoming;Song, Liubin*;Li, Lingjun;Cao, Zhong;...
通讯作者:
Song, Liubin
作者机构:
[Tang, Fuli; Xiao, Zhongliang; Liu, Jiao; Song, Liubin; Li, Xinyu; Hu, Chaoming; Cao, Zhong] Changsha Univ Sci & Technol, Sch Chem & Biol Engn, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410004, Hunan, Peoples R China.
[Zhu, Huali; Li, Lingjun] Changsha Univ Sci & Technol, Sch Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China.
通讯机构:
[Song, Liubin] C
Changsha Univ Sci & Technol, Sch Chem & Biol Engn, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410004, Hunan, Peoples R China.
语种:
英文
关键词:
Binary alloys;Cathodes;Coated materials;Coatings;Electric batteries;Electric discharges;Electrochemical properties;Electrolytes;Lithium compounds;Lithium-ion batteries;Nickel alloys;Secondary batteries;Structural optimization;Capacity retention;Cath-ode materials;Discharge capacities;Electrochemical performance;Hydrothermal methods;LiAlO2;LiNi0.8Co0.1Mn0.1O2;Structure optimization;Lithium alloys
期刊:
Ionics
ISSN:
0947-7047
年:
2018
卷:
24
期:
1
页码:
91-98
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21501015, 51604042, 31527803, 21275022, 21545010]; STS Project of the Chinese Academy of Sciences [KFJ-SW-STS-173]; Hunan Provincial Natural Science Foundation of ChinaNatural Science Foundation of Hunan Province [2016JJ3007]; Hunan Provincial Scientific Program of China [2015GK1046]; National Science & Technology Support Project of China [2012BAC17B01]
机构署名:
本校为第一且通讯机构
院系归属:
化学与生物工程学院
材料科学与工程学院
摘要:
The LiNi0.8Co0.1Mn0.1O2 with LiAlO2 coating was obtained by hydrolysis–hydrothermal method. The morphology of the composite was characterized by SEM, TEM, and EDS. The results showed that the LiAlO2 layer was almost completely covered on the surface of particle, and the thickness of coating was about 8–12nm. The LiAlO2 coating suppressed side reaction between composite and electrolyte; thus, the electrochemical performance of the LiAlO2-coated LiNi0.8Co0.1Mn0.1O2 was improved at 40°C. The LiAlO2-coated sample delivered a high discharge capac...

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