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Controllable construction of interconnected SnOx/N-doped carbon/carbon composite for enhanced-performance lithium-ion batteries anodes

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成果类型:
期刊论文
作者:
Zhu, Chao;Wei, Donghai;Wu, Yinglong;Zhang, Zeng;Zhang, Guanhua;...
通讯作者:
Duan, Junfei(段军飞);Chen, Zhaoyong
作者机构:
[Duan, Junfei; Duan, JF; Chen, Zhaoyong; Zhu, Chao; Zhang, Zeng; Zhu, Huali; Zhu, Zhiying; Wu, Yinglong; Wei, Donghai; Li, Lingjun] Changsha Univ Sci & Technol, Sch Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China.
[Zhang, Guanhua] Hunan Univ, Sch Phys & Elect, Changsha 410082, Hunan, Peoples R China.
通讯机构:
[Duan, JF; Chen, ZY] C
Changsha Univ Sci & Technol, Sch Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China.
语种:
英文
关键词:
Anodes;Carbon;Carbon carbon composites;Doping (additives);Ethanol;Ions;Nanocrystalline materials;Nanocrystals;Polypyrroles;Steam reforming;Carbonaceous species;Electrochemical performance;Ethanol steam reforming;Lithiation/delithiation;N-doped;Nanocrystallines;Rechargeable lithium ion battery;Sacrificial templates;Lithium-ion batteries
期刊:
Journal of Alloys and Compounds
ISSN:
0925-8388
年:
2019
卷:
778
页码:
731-740
基金类别:
The authors acknowledge the financial support from the National Natural Science Foundation of China (No. 21601020 , 51604042 ), Hunan Provincial Natural Science Foundation of China (No. 2016JJ3003 , 2017JJ3324 ), Hunan provincial key research and development plan (Grant No. 2016GK2012 ), Scientific Research Fund of Hunan Provincial Education Department (No. 17B002 ), Changsha City Fund for Distinguished and Innovative Young Scholars (No. KQ1707014 ). The authors acknowledge the financial support from the National Natural Science Foundation of China (No. 21601020, 51604042), Hunan Provincial Natural Science Foundation of China (No. 2016JJ3003, 2017JJ3324), Hunan provincial key research and development plan (Grant No. 2016GK2012), Scientific Research Fund of Hunan Provincial Education Department (No. 17B002), Changsha City Fund for Distinguished and Innovative Young Scholars (No. KQ1707014).
机构署名:
本校为第一且通讯机构
院系归属:
材料科学与工程学院
摘要:
Tin-based materials have been considered as promising anode materials for their high theoretical capacities in rechargeable lithium ion batteries. However, the large volume variation during repeated lithiation/delithiation processes, leads to aggregation and pulverization of active materials, which limits their practical application. Herein, a facile and effective strategy was designed to construct interconnected porous SnOx/N-doped carbon framework, using Sn(IV)-containing polypyrrole as sacrificial template/precursor followed by depositing ca...

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