MMA
start-up talent project#&#&#GXRC-18041
Fuzhou University
Fuzhou University#&#ߣT023
Hunan Provincial Natural Science Foundation of China#&#ߣJJ50652
机构署名：
本校为其他机构
院系归属：
化学与生物工程学院
摘要：
Alkyl bromide (R-Br) was employed as a starting compound (precursor) to initiate the bulk controlled radical polymerization of methyl methacrylate (MMA) under thermal condition (60 degrees C) in the presence of tetra-noctylammonium iodide (Oct(4)NI) and 2,2'-azobisisoheptonitrile (V65). Alkyl iodide (R-I) and tetraoctylammonium bromide (Oct(4)NBr) were in situ generated by the reaction of R-Br with Oct(4)NI and then R-I was employed as an initiating dormant species for the polymerization. Carbon-iodine (C-I) bonds were cleaved and radicals were generated by the catalyst of Oct(4)NI and Oct(4)N...
