期刊论文

Zheng Xing-Liang

英文

Chinese Journal of Structural Chemistry

0254-5861

2011

30

7

1074-1078

10.14102/j.cnki.0254-5861.2011.07.023

The project was supported by the National Natural Science Foundation of China （No. 20976017） and Scientific Research Fund of Hunan Provincial Science and Technology Department （No. 2009CK3070）

本校为第一且通讯机构

The title compound(7R,8S,9S,12S)-13,14-dehydro-1-(4'-fluorobenzyloxy)-N-methyl-2,13-dimethoxy-12-hydroxymorphinane was synthesized by the reaction of O-4-bromobenzylsinomenine with lithium aluminum hydride.Its chemical structure was determined by X-ray single-crystal diffraction.The crystal belongs to triclinic,space group P1 with Mr=439.51,a= 7.7236(1),b=8.7282(1),c=9.9342(2)A,α=81.176(1),β=67.43,γ=64.577(1)°,μ=0.76 mm-1,V=558.4...