期刊论文

Progress on Preparation and Application of 5-Hydroxymethylfurfural

Qi, W.

中文

林产化学与工业

0253-2417

2019

39

1

13-22

10.3969/j.issn.0253-2417.2019.01.002

国家自然科学基金资助项目(51676193) 中国科学院青年创新促进会项目(2017401) 广州市科技计划项目(201804010187).

本校为第一机构

5-羟甲基糠醛 (HMF) 被认为是最重要的生物质基平台分子之一, 广泛应用于制备精细化学品、关键医药中间体、功能聚酯、溶剂和液体燃料等多功能化合物.目前, HMF的制备是生物质领域研究的热点, 大量的研究使得制备HMF的原料和方法得到不断扩展.简单介绍了HMF的主要制备方法及其反应机理, 系统综述了制备HMF的催化体系, 包括催化过程中所使用的催化剂 (无机酸、离子液体、金属氯化物、固体酸及其他催化剂) 种类及制备HMF的溶剂体系.归纳了HMF重要衍生物的制备路径及应用, 总结了目前研究中所存在的问题, 并展望了未来的研究方向.

5-Hydroxymethylfurfural (HMF) is one of the most important biomass-based platform molecules and widely used in the preparation of multifunctional compounds such as fine chemicals, key pharmaceutical intermediates, functional polyesters, solvents and liquid fuels. At present, the preparation of HMF is a hot spot in the field of biomass research, and the raw materials and methods for preparing HMF have been continuously expanded. This paper reviews the main preparation methods and research progress of HMF. Catalysis systems for HMF preparation is systematically described, including the types of ...