期刊论文

Advances of redox-active molecules in aqueous organic redox flow batteries

中文

长沙理工大学学报(自然科学版)

1672-9331

2023

20

03

52-68

10.19951/j.cnki.1672-9331.20221207001

2020JJ5569:湖南省自然科学基金资助项目 21A0195:湖南省教育厅科学研究项目 21C0215:湖南省教育厅科学研究项目

本校为第一机构

作为一种极具潜力的大规模储能设备，氧化还原液流电池（redox flow batteries,RFBs）近十年来发展迅速。与传统水系无机RFBs（以钒、锌、铁、卤素等无机离子为氧化还原活性分子）相比，水系有机氧化还原液流电池（aqueous organic redox flow batteries,AORFBs）的电化学活性分子种类更多、来源更广，AORFBs已成为RFBs领域中的研究热点。此外，有机分子所具有的结构易修饰、电化学窗口灵活可调的优势，使AORFBs有望突破传统水系RFBs的功率和能量密度。然而，目前有机分子的稳定性差和溶解度低等问题使AORFBs的实际寿命和运行成本仍无法与钒液流电池的相比。为此，研究者们做了大量工作，本文综...

As a promising large-scale energy storage technology,redox flow batteries(RFBs)have been developed rapidly in recent ten years.Compared with the traditional aqueous inorganic RFBs(which take vanadium,zinc,iron,halogen or other inorganic ions as redox-active molecules),a...MORE As a promising large-scale energy storage technology,redox flow batteries(RFBs)have been developed rapidly in recent ten years.Compared with the traditional aqueous inorganic RFBs(which take vanadium,zinc,iron,halogen or other inorganic ions as redox-active molecules),aqueous organic redox flow batteries(AORFBs)have more...