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Formation mechanism of n-octadecane @ calcium fluoride microencapsulated phase change material

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成果类型:
期刊论文
作者:
Ping Hu;Ye Tan;You-Tong Zhu;Rong Chen;Sheng-Ci Cui;...
通讯作者:
Ye Tan<&wdkj&>Ju-Lan Zeng
作者机构:
[Ye Tan; You-Tong Zhu; Rong Chen; Sheng-Ci Cui; Qi Wang; Lin-Ping Yu; Ju-Lan Zeng] Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Hunan Provincial Key Laboratory of Cytochemistry, School of Chemistry and Chemical Engineering, Changsha University of Science and Technology, Changsha 410114, PR China
Hunan Xiangli Salt Chemical Co, Ltd, Jinshi 415400, PR China
[Chuan-Chang Li] School of Energy and Power Engineering, Changsha University of Science and Technology, Changsha 410114, PR China
[Ping Hu] Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Hunan Provincial Key Laboratory of Cytochemistry, School of Chemistry and Chemical Engineering, Changsha University of Science and Technology, Changsha 410114, PR China<&wdkj&>Hunan Xiangli Salt Chemical Co, Ltd, Jinshi 415400, PR China
通讯机构:
[Ye Tan; Ju-Lan Zeng] H
Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Hunan Provincial Key Laboratory of Cytochemistry, School of Chemistry and Chemical Engineering, Changsha University of Science and Technology, Changsha 410114, PR China
语种:
英文
期刊:
Journal of Energy Storage
ISSN:
2352-152X
年:
2024
卷:
85
页码:
111124
基金类别:
The photos of the prepared MPCMs samples with NaBF4 (MPCM-45-F4) and KF as fluorine source, respectively, before and after they were heated at 50 °C are showed in Fig. 1. The figure revealed that the leakage of MPCM-45-F4 was negligible during the heating process. However, the large wet area on the filter paper below the MPCM with KF as fluorine source indicated the sample leaked seriously. It should be noted that when KF was used, all the obtained samples exhibited severe leakage, even the
机构署名:
本校为第一且通讯机构
院系归属:
能源与动力工程学院
化学与生物工程学院
摘要:
Microencapsulating phase change materials (PCMs) with CaF2 as shell could obtain not only novel microencapsulated PCMs (MPCMs) but also potential luminescence materials with self-thermal regulation property. Prior to the preparation of good luminescent MPCMs with doped CaF2 as shell, the formation mechanism of the MPCMs should be well understood. In this work, n-octadecane (ODE) was selected as core to prepare CaF2 MPCMs and the formation mechanism was comprehensively investigated. The results revealed that the concentrations of the Ca2+ and th...

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