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Mesoporous Si/C composite anode material: experiments and first-principles calculations

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成果类型:
期刊论文
作者:
Xiao, Zhongliang;Xia, Ni;Song, Liubin*;Cao, Zhong;Zhu, Huali
通讯作者:
Song, Liubin
作者机构:
[Xia, Ni; Xiao, Zhongliang; Song, Liubin; Cao, Zhong] Changsha Univ Sci & Technol, Sch Chem & Food Engn, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410004, Hunan, Peoples R China.
[Zhu, Huali] Changsha Univ Sci & Technol, Sch Phys & Elect Sci, Changsha 410004, Hunan, Peoples R China.
通讯机构:
[Song, Liubin] C
Changsha Univ Sci & Technol, Sch Chem & Food Engn, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410004, Hunan, Peoples R China.
语种:
英文
关键词:
Amines;Anodes;Calculations;Coated materials;Energy gap;Expansion;Graphene;Lithium-ion batteries;Molten materials;Silica;Anode material;Coated composites;First-principles calculation;Initial Coulombic efficiency;Magnesiothermic reduction;Mesoporous carbon;Mesoporous silicon;Mesoporous structures;Mesoporous materials
期刊:
Ionics
ISSN:
0947-7047
年:
2020
卷:
26
期:
2
页码:
589-599
基金类别:
This work was financially supported by the National Natural Science Foundation of China (Nos. 21501015, 51604042, 31527803, 51774051, and 21545010).
机构署名:
本校为第一且通讯机构
院系归属:
化学与生物工程学院
物理与电子科学学院
摘要:
Carbon-coated and doped mesoporous silicon/carbon (m-Si/C) composites were successfully prepared via carbon coating and molten magnesiothermic reduction by using mesoporous silica (SBA-15) and dopamine as raw materials. Experimental results were theoretically verified by first-principles calculation. The obtained m-Si/C composites exhibited a high initial Coulombic efficiency of 73% at 0.1Ag−1 and an excellent cycling stability with 617.5mAhg−1 capacity after 100cycles at 0.1Ag−1. This excellent performance was attributed to the combination ...

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