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Effect of Controlled-Atmosphere Storage and Ethanol Rinsing on NaNi0.5Mn0.5O2 for Sodium-Ion Batteries

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成果类型:
期刊论文
作者:
Zheng, Lituo;Li, Lingjun;Shunmugasundaram, Ramesh;Obrovac, M. N.*
通讯作者:
Obrovac, M. N.
作者机构:
[Obrovac, M. N.; Zheng, Lituo; Shunmugasundaram, Ramesh; Li, Lingjun] Dalhousie Univ, Dept Chem, Halifax, NS B3H 4R2, Canada.
[Li, Lingjun] Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China.
通讯机构:
[Obrovac, M. N.] D
Dalhousie Univ, Dept Chem, Halifax, NS B3H 4R2, Canada.
语种:
英文
关键词:
sodium-ion batteries;layered cathode material;NaNi0.5Mn0.5O2;air sensitivity;surface modification;ethanol rinse;surface impurities
期刊:
ACS Applied Materials & Interfaces
ISSN:
1944-8244
年:
2018
卷:
10
期:
44
页码:
38246-38254
基金类别:
The authors acknowledge funding from NSERC and 3M Canada, Co. under the auspices of the Industrial Research Chair and Discovery Grant Programs. We also acknowledge the support of the Canada Foundation for Innovation, the Atlantic Innovation Fund, and other partners that fund the Facilities for Materials Characterization managed by the Institute for Research in Materials. L.L. acknowledges the support from China Scholarship Council.
机构署名:
本校为其他机构
院系归属:
材料科学与工程学院
摘要:
NaNi0.5Mn0.5O2 is a promising sodium-ion battery cathode material that has been extensively studied. However, the air sensitivity of this material limits practical application and is not well understood. Here, we present a detailed study of NaNi0.5Mn0.5O2 powders stored in different atmospheres (oxygen, argon, and carbon dioxide), either dry or wet. X-ray diffraction and Fourier transform infrared measurements were used to characterize the materials and their surface species before and after controlled-atmosphere storage. It was determined that the exposure of untreated NaNi0.5Mn0.5O2 powders ...

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